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  1. Glass transition - Wikipedia

    • The glass–liquid transition, or glass transition, is the gradual and reversible transition in amorphous materials (or in amorphous regions within semicrystalline materials) from a hard and relatively brittle "glassy" state into a viscous or rubbery state as the temperature is increased. An amorphous solid that exhibits a glass transition is called a glass. The reverse tra… See more

    Characteristics

    The glass transition of a liquid to a solid-like state may occur with either cooling or compression. The transition comprises … See more

    Formal definitions

    The definition of the glass and the glass transition are not settled, and many definitions have been proposed over the past century.
    Franz Simon: Glass is a rigid material obtained fr… See more

    Transition temperature Tg

    Refer to the figure on the bottom right plotting the heat capacity as a function of temperature. In this context, Tg is the temperature corresponding to point A on the curve.
    Different op… See more

    Linear heat capacity

    In 1971, Zeller and Pohl discovered that when glass is at a very low temperature ~1K, its specific heat has a linear component: . This is an unusual effect, because crystal material typically has , as in the … See more

    Kauzmann's paradox

    As a liquid is supercooled, the difference in entropy between the liquid and solid phase decreases. By extrapolating the heat capacity of the supercooled liquid below its glass transition temperature, it is possible to calculat… See more

    In specific materials

    Silica (the chemical compound SiO2) has a number of distinct crystalline forms in addition to the quartz structure. Nearly all of the crystalline forms involve tetrahedral SiO4 units linked together by shared vertices in different arr… See more

    Mechanics of vitrification

    Molecular motion in condensed matter can be represented by a Fourier series whose physical interpretation consists of a superposition of longitudinal and transverse waves of atomic displacement with varying directions a… See more

     
  1. When the perturbation frequency imposed on a rubber falls within the glass transition zone of its viscoelastic spectrum, energy absorption is maximized. This phenomenon is the operative mechanism for various applications of elastomers requiring large energy dissipation.
    Author: C. Michael Roland
    Publish Year: 2012
    meridian.allenpress.com/rct/article/85/3/313/93309/GLASS-TRANSITION-IN-RUBBERY-MATERIALS
    meridian.allenpress.com/rct/article/85/3/313/93309/GLASS-TRANSITION-IN-R…
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  2. Polymer Chemistry: The Glass Transition - Engineering …

    When an amorphous polymer is heated, the temperature at which it changes from a glass to the rubbery form is called the glass transition temperature, T g. A given polymer sample does not have a unique value of T g because the glass phase …

  3. 4.4: Glass Transition - Chemistry LibreTexts

  4. Understanding Glass Transition Temperature: Part 1

  5. Kinetics of the Glass Transition of Silica-Filled Styrene–Butadiene ...

  6. GLASS TRANSITION IN RUBBERY MATERIALS | Rubber Chemistry …

  7. Glass Transition Parameters of Polyisoprene Rubbers: Differential ...

  8. Journal of Applied Polymer Science | Wiley Online Library

    Aug 12, 2020 · The glass transition is relevant for performance definition in rubber products. For extrapolation to high-frequency behavior, time–temperature superposition is usually assumed, although most complex rubber compounds …